有机合成指南（第3版）

图书标准信息

• 作者 D.M.Smith et、R.K Mackie 编
• 出版社 世界图书出版公司
• 出版时间 2001-04
• 版次 3
• ISBN 9787506250337
• 定价 46.00元
• 装帧 平装
• 开本 其他
• 纸张 胶版纸
• 页数 387页
• 正文语种 英语

【目录】

1Introduction
2Functionalgroupchemistry:thebasics
2.1Selectivityoforganicreactions
2.2Functionalizationofalkanes
2.3Functionalizationofalkencs
2.4Functionalizationofalkynes
2.5Functionalizationofaromatichydrocarbons
2.6Functionalizationofsubstitutedbenzenederivatives
2.7Functionalizationofsimpleheterocycliccompounds
2.8InterconversionoffunctionalgroupsSummary
3Formationofcarbon-carbonbonds:theprinciples
3.1Generalstrategy
3.2Disconnectionsandsynthons
3.3Electrophiliccarbonspecies
3.4NucleophiliccarbonspeciesSummary
4Formationofcarbon-carbonbonds:reactionsoforganometallic
compounds
4.1Grignardreagentsandelectrophiles
4.2Otherorganometallicreagentsandelectrophiles
4.3Reactionsofnucleophilesderivedfromalk-l-ynes
4.4Review
4.5WorkedexamplesSummary
5Formationofcarbon-carbonbonds:theuseofstabilizedcarbanions
andrelatednucleophiles
5.1Carbanionsstabilizedbytwo-Mgroups
5.2Carbanionsstabilizedbyone-Mgroup
5.3Carbanionsstabilizedbyneighbouringphosphorusorsulfur
5.4Nucleophilicacylation
5.5Alkene,areneandheteroarenenucleophiles
5.6Review
5.7WorkedexamplesSummary
6Formationofcarbon-heteroatombonds:theprinciples
6.1Carbon-halogenbonds
6.2Carbon-oxygen,carbon-sulfurandcarbon-seleniumbonds
6.3Carbon-nitrogenandcarbon-phosphorusbonds
6.4Carbon-siliconbondsSummary
7Ringclosure（andringopening）
7.1lntramolecularcyclizationbyelectrophile-nucleophileinteraction
7.2Cycloaddition
7.3Electrocyclicringclosure
7.4Ringopening
7.5Review
7.6WorkedexamplesSummary
8Reduction
8.1Catalytichydrogenation
8.2Metalhydridereductions
8.3Electron-transferreactions
8.4Reductionofspecificfunctionalgroups
8.5Reductivecleavageofcarbon-heteroatombonds
8.6Reductiveringopeningofoxiranes
8.7ReductionOfa/B-unsaturatedcarbonylcompounds
8.8Reductionofconjugateddienes
8.9ReductionofaromaticandheteroaromaticcompoundsSummary
……
9Oxidation
10Protectivegroups
11Boronreagents
12Phosphorusreagents
13Siliconreagents
14Seleniumreagents
15Asymmetricsynthesis
16Selectedsynthese
Endnotestothetext
Furtherreading
Index