目录 Preface Author biography 1 Introduction References Background and nomenclature: the ideal gas References 3 van der Waals intermolecular interaction parameters 4 Thermodynamic variables and properties in terms of the van der Waals interaction parameters 4.1 Helmholtz flee energy 4.2 Critical pressure, temperature and volume 4.3 Entropy, internal energy and heat capacity at constant volume 4.4 Pressure and enthalpy 4.5 Chemical potential Reference 5 van der Waals equation of state, reduced variables and laws of corresponding states 5.1 van der Waals equation of state and reduced variables 5.2 Laws of corresponding states 5.3 Pressure versus volume and versus density isotherms 5.4 Influence of the van der Waals interactions on the pressure of the gas phase 5.5 Boyle temperature 5.6 Thermodynamic properties expressed in reduced variables 5.6.1 Internal energy 5.6.2 Helmholtz free energy 5.6.3 Entropy and enthalpy 5.6.4 Isothermal compressibility 5.6.5 Volume thermal expansion coefficient 5.6.6 Heat capacity at constant pressure 5.6.7 Chemical potential References 6 Equilibrium pressure-volume, temperature-volume and pressure-temperature phase diagrams 6.1 Pressure-volume phase diagram and Maxwell construction 6.2 Volume-temperature phase diagram 6.3 Lever rule 6.4 Pressure-temperature phase diagram References 7 Lekners parametric solution of the coexistence curve and associated properties 7.1 Thermodynamic behaviors on approaching the critical temperature from below 7.2 Thermodynamic behaviors for temperatures approaching zero 7.3 Coexisting liquid and gas densities, transition order parameter and temperature-density phase diagram 7.4 Latent heat and entropy of vaporization 7.5 Heat capacity at constant volume versus temperature within the liquid-gas coexistence region along an isochoric path References 8 Static critical exponents 8.1 Heat capacity at constant volume 8.2 Pressure versus volume isotherm at the critical temperature 8.3 Critical chemical potential isotherm versus number density 8.4 Liquid-gas transition order parameter 8.5 Isothermal compressibility 8.5.1 Approach to the critical point along the critical isochore from above the critical temperature
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