目录 Contents 目.录 Part 1 Experimental Organic Chemistry Chapter 1 General Introduction........................................................................................................................................ 3 1. Laboratory Rules................................................................................................................................................................... 3
2. Safety Rules and Regulations in Chemistry Laboratory ................................................................................................. 3
3. Treatment of the Common Accidents in Laboratory....................................................................................................... 5
4. Fire Prevention and Treatment ........................................................................................................................................... 5
5. First Aid Kit............................................................................................................................................................................ 5
6. Preview, Record and Laboratory Report........................................................................................................................... 5 Chapter 2 Common laboratory Apparatus and Equipment ............................................................................... 7
1. General Glassware ................................................................................................................................................................ 7
2. Common Standard-taper Glassware.................................................................................................................................. 7
3. Common Glass Apparatus................................................................................................................................................... 8
4. Common Equipment ............................................................................................................................................................ 8 Chapter 3 Laboratory Experiments.............................................................................................................................. 11 Experiment 1 Basic Laboratory Techniques (Ⅰ) ............................................................................................................... 11 Experiment 2 Basic Laboratory Techniques (Ⅱ) ............................................................................................................. 14 Experiment 3 Extraction of Iodine..................................................................................................................................... 16 Experiment 4 Determination of the Melting Point.......................................................................................................... 18 Experiment 5 Micro Determination of the Boiling Point................................................................................................ 19 Experiment 6 Refractive Index Determination of Liquid Organic Compound .......................................................... 21 Experiment 7 Operation of Organic Molecular Models................................................................................................. 23 Experiment 8 Paper Electrophoresis of Amino Acid...................................................................................................... 25 Experiment 9 Column Chromatography.......................................................................................................................... 27 Experiment 10 Thin-Layer Chromatography (TLC) ....................................................................................................... 29 Experiment 11 Paper Chromatography............................................................................................................................ 31 Experiment 12 Preparation of Aspirin .............................................................................................................................. 34 Experiment 13 Preparation of Acetanilide ....................................................................................................................... 36 Experiment 14 Extraction of Rutin and Recovery of Extraction Agent........................................................................ 38 Experiment 15 Analysis of Unknown Sample of Organic Compounds (Designing Experiment)........................... 39
Part 2 Solutions Manual for Organic Chemistry Chapter Introduction........................................................................................................................................................ 43 Chapter Saturated Hydrocarbons: Alkanes and Cycloalkanes ................................................................... 45 Chapter Unsaturated Hydrocarbons: Alkenes, Alkynes and Aromatics................................................. 48 Chapter Alcohols, Phenols, and Ethers.................................................................................................................... 51 Chapter Aldehydes and Ketones ................................................................................................................................. 55 Chapter Carboxylic Acids and Acid Derivatives................................................................................................. 59 Chapter Amines ................................................................................................................................................................... 64 Chapter Optical Isomerism............................................................................................................................................ 66 Chapter Carbohydrate..................................................................................................................................................... 70 Chapter Lipids................................................................................................................................................................... 73 Chapter Proteins ............................................................................................................................................................... 76 Chapter Nucleic Acids.................................................................................................................................................... 79
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