光电子光谱学：原理和应用（第3版）

图书标准信息

• 作者 胡夫尼 著
• 出版社 世界图书出版公司
• 出版时间 2009-03
• 版次 3
• ISBN 9787506292771
• 定价 88.00元
• 装帧 平装
• 开本 24开
• 纸张 胶版纸
• 页数 662页
• 正文语种 英语

【内容简介】

　　SincethecompletionofthemanuscriptforthefirsteditionofPhotoelectronSpectroscopy，thefieldhasundergoneasteadygrowth.Firstly，thetheoryhasbeenrefinedandcondensedintoamanageableform.Secondlytwoimportantexperimentaldevelopmentshaveoccurred.Theresolutionthatcanbeobtainedisnowoftheorderof3meV，whichcorre-spondsapproximatelytoanenergyof30kBK.Thismeansthatphotoelectronspectroscopycannowobtaindatawithanaccuracysimilartothatachievedinstandardthermodynamicexperiments（suchasspecificheatexperiments），thusfacilitatingadirectcomparisonofdatafromthetwodifferenttypesofexperiment.ThesecondimportantexperimentaladvanceisthatonecannowreadilymeasureelectronenergydistributionsoverasolidangleofalmostThisyieldsvaluableinformationwhenevertheseelectronenergydistributionshaveanisotropies.

【目录】

1．IntroductionandBasicPrinciples
1．1HistoricalDevelopment
1．2TheElectronMeanFreePath
1．3PhotoelectronSpectroscopyandInversePhotoelectronSpectroscopy
1．4ExperimentalAspects
1．5VeryHighResolution
1．6TheTheoryofPhotoemission
1．6．1Core-LevelPhotoemission
1．6．2Valence-StatePhotoemission
1．6．3Three-StepandOne-StepConsiderations
1．7DeviationsfromtheSimpleTheoryofPhotoemission
References

2．CoreLevelsandFinalStates
2．1Core-LevelBindingEnergiesinAtomsandMolecules
2．1．1TheEquivalent-CoreApproximation
2．1．2ChemicalShifts
2．2Core-LevelBindingEnergiesinSolids
2．2．1TheBorn-HaberCycleinInsulators
2．2．2TheoryofBindingEnergies
2．2．3DeterminationofBindingEnergiesandChemicalShiftsfromThermodynamicData
2．3CorePolarization
2．4Final-StateMultipletsinRare-EarthValenceBands
2．5VibrationalSideBands
2．6CoreLevelsofAdsorbedMolecules
2．7QuantitativeChemicalAnalysisfromCore-LevelIntensities
References

3．Charge-ExcitationFinalStates：Satellites
3．1CopperDihalides;3dTransitionMetalCompounds
3．1．1CharacterizationofaSatellite
3．1．2AnalysisofCharge-TransferSatellites
3．1．3Non-localScreening
3．2The6-eVSatelliteinNickel
3．2．1ResonancePhotoemission
3．2．2SatellitesinOtherMetals
3．3TheGunnarsson-Sch6nhammerTheory
3．4PhotoemissionSignalsandNarrowBandsinMetals
References

4．ContinuousSatellitesandPlasmonSatellites：XPSPhotoemissioninNearlyFreeElectronSystems
4．1Theory
4．1．1General
4．1．2Core-LineShape
4．1．3IntrinsicPlasmons
4．1．4FxtrinsicFAectronScattering：PlasmonsandBackground
4．1．5TheTotalPhotoelectronSpectrum
4．2ExperimentalResults
4．2．1TheCoreLineWithoutPlasmons
4．2．2Core-LevelSpectraIncludingPlasmoas
4．2．3Valence-BandSpectraoftheSimpleMetals
4．2．4SimpleMetals：AGeneralComment
4．3TheBackgroundCorrection
References

5．ValenceOrbitalsinSimpleMoleculesandInsulatingSolids
5．1UPSSpectraofMonatomicGases
5．2PhotoelectronSpectraofDiatomicMolecules
5．3BindingEnergyoftheH2Molecule
5．4HydridesIsoelectronicwithNobleGases
Neon(Ne)
HydrogenFluoride(HF)
Water(H2O)
Ammonia(NH3)
Methane(CH4)
5．5SpectraoftheAlkaliHMides
5．6TransitionMetalDihalides
5．7Hydrocarbons
5．7．1GuidelinesfortheInterpretationofSpectrafromFreeMolecules
5．7．2LinearPolymers
5．8InsulatingSolidswithValencedElectrons
5．8．1TheNiOProblem
5．8．2MortInsulation
5．8．3TheMetal-InsulatorTransition；theRatiooftheCorrelationEnergyandtheBandwidth；Doping
5．8．4BandStructuresofTransitionMetalCompounds
5．9High—TemperatureSuperconductors
5．9．1valence-BandElectronicStructure；PolycrystallineSamples
5．9．2DispersionRelationsinHighTemperatureSuperconductors；SingleCrystals
5．9．3TheSuperconductingGap
5．9．4SymmetryoftheOrderParameterintheHigh-TemperatureSuDerconductors
5．9．5Core—LevelShifts
5．10TheFermiLiquidandtheLuttingerLiquid
5．11AdsorbedMolecules
5．11．1Outline
5．11．2COonMetalSurfaces
References

6．PhotoemissionofValenceElectronsfroillMetallicSolidsintheOHe-ElectronApproximation
6．1TheoryofPhotoemission：ASummaryoftheThree-StepModel
6．2DiscussionofthePhotocurrent
6．2．1KinematicsofInternalPhotoemissioninaPolycrystallineSample
6．2．2PrimaryandSecondaryConesinthePhotoemissionfromaRealSolid
6．2．3Angle-IntegratedandAngle-ResolvedDataCollection
6．3PhotoemissionfromtheSemi—infiniteCrystal：TheInverseLEEDFormalism
6．3．1BandStructureRegime
6．3．2XPSRegime
6．3．3SurfaceEmission
6．3．4One-StepCalculations
6．4ThermalEffects
6．5DipoleSelectionRulesforDirectOpticalTransitions
References

7．BandStructtireandAngular-ResolvedPhotoelectronSpectra
7．1Free-ElectronFinal—StateModel
7．2MethodsEmployingCalculatedBandStructures
7．3MethodsfortheAbsoluteDeterminationoftheCrystalMomentum
7．3．1TriangulationorEnergyCoincidenceMethod
7．3．2BraggPlaneMethod：VariationofExternalEmissionAngleatFixedPhotonFrequency(Disappearance/AppearanceAngleMethod
7．3．3BraggPlaneMethod：VariationofPhotonEnergyatFixedEmissionAngle(SymmetryMethod)
7．3．4TheSurfaceEmissionMethodandElectronDamping
7．3．5TheVery-Low-EnergyElectronDiffractionMethod
7．3．6TheFermiSurfaceMethod
7．3．7IntensitiesandTheirUseinBand-StructureDeterminations
7．3．8Summary
7．4ExperimentalBandStructures
7．4．1One-andTwo-DimensionalSystems
7．4．2Three-DimensionalSolids：MetalsandSemiconductors
7．．4．3UPSBandStructuresandXPSDensityofStates
7．5AComment
References

8．SurfaceStates，SurfaceEffects
8．1TheoreticalConsiderations
8．2ExperimentalResultsonSurfaceStates
8．3Quantum-WellStates
8．4SurfaceCore-LevelShifts
References

9．InversePhotoelectronSpectroscopy
9．1SurfaceStates
9．2BulkBandStructures
9．3AdsorbedMolecules
References

10．Spin-PolarizedPhotoelectronSpectroscopy
10．1GeneralDescription
10．2ExamplesofSpin-PolarizedPhotoelectronSpectroscopy
10．3MagneticDichroism
References

11．PhotoelectronDiffraction
11．1Examples
11．2SubstratePhotoelectronDiffraction
11．3AdsorbatePhotoelectronDiffraction
11．4FermiSurfaceScans
References

Appendix
A．1TableofBindingEnergies
A．2SurfaceandBulkBrillouinZonesoftheThreeLow-IndexFacesofaFace—CenteredCubic(fcc)CrystalFace
A．3CompilationofWorkFunctions
References
Index