高分子化学原理

图书标准信息

• 作者 P..Flory 著
• 出版社 世界图书出版公司
• 出版时间 2003-06
• 版次 1
• ISBN 9787506260169
• 定价 68.00元
• 装帧 平装
• 开本 其他
• 纸张 胶版纸
• 页数 672页

【内容简介】

《高分子化学原理(英文版)》由世界图书出版公司出版，内容包括：
HISTORICALINTRODUCTl0N、TYPES0FPOLYMERICSUBSTANCES：DEFINITIONSAND、MOLECULARSIZEANDCHEMICALREACTIVITY；PRINCIPLESOFCONDENSATIONPOLYMERIZATION、POLYMERIZATIONOFUNSATURATEDMONOMERSBYFREERADICALMECHANISMS、COPOLYMERIZATION,EMULSIONPOLYMERIZATIONANDIONICPOLYMERIZATION、THESTRUCTUREOFVINYLPOLYMERS等。

【目录】

Preface
CHAPTERⅠHISTORICALINTRODUCTl0N
1.EarlyInvestigationsonNaturaUyOccurringPolymers
2.EarlyEncounterswithCondensationPolymers
3.VinylPolymers
4.RiseoftheMacromoleoularHypothesis
References.

CHAPTERⅡTYPES0FPOLYMERICSUBSTANCES：DEFINITIONSANDCLASSIFICATIONS
1.PrimaryDefinitions
2.ClassificationofPolymers
3.CondensationPolymersandCondensationPolymerization
4.AdditionPobrmersfromUnsaturatedMonomers
5.PolymerizationofCyclicCompounds
6.AnomalousConden8ationPolymerizations
7.InorganicPolymers
8.ConcludingRemarksontheStructureandPropertiesofHighPolymers
References.

CHAPTERⅢMOLECULARSIZEANDCHEMICALREACTIVITY；PRINCIPLESOFCONDENSATIONPOLYMERIZATION
1.ChemicalReactivityinHomologousSeriesofMonomericCom—pouuds
2.TheoryoftheReactivityofLargeMolecules
3.KineticsofCondensationPolymerization
4.KineticsofDegradationofCondensationPolymers
4a.HydrolysisofCelluloseandCelluloseDerivatives
4b.HydrolysisofPolyamides
4c.AlcoholysisofPolyesters
4d.InterchangeReactionsinCondensationPolymers
5.MolecularWeightsofLinearCondensationPolymers
6.RingFormationvs.ChainPolymerization
7.SummaryandConclusions：ThePrincipleofEqualReactivityofAllFunctionalGroups
References.

CHAPTERⅣPOLYMERIZATIONOFUNSATURATEDMONOMERSBYFREERADICALMECHANISMS
1.TheConversionofMonomertoPolymer
1a.KineticSchemeforPolymerizationinthePresenceofanInitiator
1b.DependenceofInitialRatesontheConcentrationsofIniti-atorandMonomer
1c.InitiatorEfficiencies
1d.EvaluationofParameters
1e.TheCourseoftheConversionofMonomertoPolymer;Autoacceleration
1f.KineticsofThermalPolymerization
2.ChainLengths
2a.KineticChainLengthandDegreeofPolymerization
2b.KineticsofChainTransfer.
2c.ChainTransferinUndilutedMonomer;EvaluationofParameters
2d.ChainTransferwithSolvents
2e.DependenceoftheDegreeofPolymerizationonTempera-ture
2f.Regulators
3.AbsoluteValuesoftheRateConstantsforIndividualSteps
3a.MethodsforDeterminingtheMeanLifetimeofanActiveCenter.
3b.ExperimentalResults
4.InhibitionandRetardationofPolymerization
4a.ReactionMechanisms
4b.KineticsofInhibitionandRetardation
4c.AllylicPolymerization;Autoinhibition
References.
CHAPTERⅤCOPOLYMERIZATION，EMULSIONPOLYMERIZATIONANDIONICPOLYMERIZATION
CHAPTERⅥTHESTRUCTUREOFVINYLPOLYMERS
CHAPTERⅦDETERMINATIONOFMOLECULARWEIGHTS
CHAPTERⅧMOLECULARWEIGHTDISTRIBUTIONSINLINEARPOLYMERS
CHAPTERⅨMOLECULARWEIGHTDISTRIBUTIONSINNONLINEAR
CHAPTERⅩCONFIGTURATIONOFPOLYMERCHAINS
CHAPTERⅪRUBBERELASTICITY
CHAPTERⅫSTATISTICALTHERMODYNAMICSOFPOLYMERSOLUTIONS
CHAPTERXIIIPHASEEQUILIBRIAINPOLYMERSYSTEMS
CHAPTERXIVCONFIGURATIONALANDFRICTIONALPROPERTIESOFTHEPOLYMERMOLECULEINDILUTESOLUTION
GLOSSARYOFPRINCIPALSYMBOLS
AUTHORINDEX
SUBJECTINDEX