Polymer Chemistry
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作者周明,代加林 编
出版社化学工业出版社
ISBN9787122340481
出版时间2019-06
版次1
装帧平装
开本16开
纸张胶版纸
页数185页
定价48元
上书时间2024-08-18
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基本信息
书名:Polymer Chemistry
定价：48.00元
作者:周明,代加林 编
出版社：化学工业出版社
出版日期：2019-06-01
ISBN：9787122340481
字数：
页码：185
版次：1
装帧：平装
开本：16开
商品重量：
编辑推荐
《Polymer Chemistry（双语教学用）》作为双语教学的英文教材，注重启发，易于理解和接受，习题典型；科学性、实践性和综合性都很强，具有使用价值。
内容提要
The textbook is divided into eight chapters.In the introduction,the basic concept of polymer,classification and nomenclature of polymer,reaction type of polymer,development history of polymer and application of polymer are introduced in brief.In the next six chapters,free radical polymerization,free radical copolymerization,ionic polymerization,step polymerization,ring-opening polymerization and chemical reactions of polymers are introduced in detail.The implementation methods of polymerization are introduced systematically in the last chapter.The new words and terminology are noted in Chinese in detail,and the large exercises are attached at the end of each chapter,which is helpful for the students who are new to polymer chemistry to study smoothly. This book is used as the textbook for colleges and universities.It is suitable for the major of Polymer Materials and Engineering,Material Chemistry,Material Science and Engineering,New Energy Materials and Devices,New Energy Materials and Engineering,Chemical Engineering and Technology,Applied Chemistry in engineering,Chemistry,Organic Chemistry,Analytical Chemistry,Polymer Chemistry and Polymer Physics in science,and Chemistry in normal colleges.It can also be used as the reference for junior college,scientific researchers and production technicians. 《Polymer Chemistry(双语教学用)》共分8章。首先在绪论中介绍了聚合物的基本概念、聚合物的分类和命名、聚合物的反应类型、聚合物的发展历程、聚合物的应用等。接下来6章分别就自由基聚合、自由基共聚、离子聚合、逐步聚合、开环聚合、聚合物的化学反应进行详细介绍。最后1章较系统地介绍聚合实施方法。书中对专业生词和专业术语做了较详细的中文注解，另每章后都附有习题，有利于初接触到高分子化学的学生顺利学习。 本书适合作为高等院校教材，适用于工科的高分子材料与工程、材料化学、材料科学与工程、新能源材料与器件、新能源材料与工程、化学工程与工艺和应用化学专业，理科的化学、有机化学、分析化学、高分子化学及物理专业，师范院校的化学专业。也可供大专院校师生以及科研人员和生产技术人员参考。
目录
Chapter 1 INTRODUCTION11.1BASIC CONCEPTS AND DEFINITIONS11.1.1Monomers and Polymers11.1.2Structural Unit and Repeating Unit21.1.3Dimers,Trimers and Oligomers31.1.4Linear Polymers31.1.5Branched Polymers41.1.6Crosslinked Polymers41.1.7Stars and Dendrimers41.1.8Ladder Polymers51.1.9Copolymers51.2AVERAGE MOLECULAR WEIGHT AND DISTRIBUTION71.3TYPES OF POLYMERS AND POLYMERIZATIONS91.3.1Condensation Reactions91.3.2Addition Reactions101.3.3Ring-opening Polymerizations101.4POLYMERIZATION MECHANISM111.4.1Step Polymerization111.4.2Chain Polymerization111.4.3Comparison of Step and Chain Polymerization121.5NOMENCLATURE OF POLYMERS131.5.1Nomenclature Based on Source131.5.2Nomenclature Based on Structure(Non-IUPAC)141.5.3Trade Name141.5.4IUPAC Structure-Based Nomenclature System151.6A BRIEF HISTORY OF SYNTHETIC POLYMERS161.6.11838-1930’s161.6.21930-1945’s171.6.31945-1960’s171.6.41960-1980’s181.6.51980-2000’s181.6.62000-2018’s191.6.7Prospect of Polymer Materials191.7HISTORY OF NOBEL PRIZES FOR POLYMER SCIENCE201.8APPLICATION OF POLYMERS20Exercises1 21Chapter 2 FREE-RADICAL POLYMERIZATION232.1INTRODUCE232.1.1Initiators242.1.2Monomers252.1.3Solvents and Systems262.2INITIATION272.2.1Initiation by Thermal Decomposition of Initiators272.2.2Initiation by Redox Reactions292.2.3Initiation by Photolytic and Ionizing Radiation292.2.4Reactions of Initiator Radicals with Monomers292.3RADICAL CHAIN PROPAGATION302.4CHAIN TRANSFER REACTIONS312.5FREE RADICAL CHAIN TERMINATION322.6KINECTICS OF FREE RADICAL POLYMERIZATION332.6.1Appromations342.6.2Steady-state Concentrations of the Propagating Radicals352.6.3Theoretic Rate of Polymerization362.7AVERAGE KINETIC CHAIN LENGTH392.8AVERAGE DEGREE OF POLYMERIZATION AND AVERAGE MOLECULAR WEIGHT402.9EFFECT OF CHAIN TRANSFER ON AVERAGE DEGREE OF POLYMERIZATION412.10DEPENDENCE OF THE DEGREE OF POLYMERIZATION ON TEMPERATURE432.11DISTRIBUTION OF MOLECULAR WEIGHT442.11.1Disproportionation Termination442.11.2Combination Termination452.12INHIBITOR AND RETARDER46Exercises2 47Chapter 3 FREE-RADICAL COPOLYMERIZATION513.1TYPES AND NAMENCLATURE OF COPOLYMERS513.2REACTIVITY RATIO AND COPOLYMER COMPOSITION EQUATION523.3COPOLYMERIZATION BEHAVIOR543.3.1Ideal Copolymerization543.3.2Alternating Copolymerization563.3.3Non-ideal Copolymerization563.3.4"Block" Copolymerization573.4EXPERIMENTAL DETERMINATION OF ACTIVITY RATIOS573.5VARIATION OF COPOLYMER COMPOSITION WITH CONVERSION583.6EFFECT OF MONOMER STRUCTURE ON REACTIVITY603.6.1Conjugation Effect603.6.2Polarity Effect603.6.3Steric Effect613.7Q-e EQUATIONS613.8DISTRIBUTION OF MONOMERS IN A COPOLYMER63Exercises3 65Chapter 4 IONIC POLYMERIZATION674.1ANIONIC POLYMERIZATION684.1.1Initiators for Anionic Polymerization684.1.2Monomers for Anionic Polymerization704.1.3Solvents704.1.4The Mechanism of Anionic Polymerization(General)714.1.5Living Polymers and Copolymerization724.2COORDINATION POLYMERIZATION734.2.1Ziegler-Natta Catalyst734.2.2Composition of the Catalyst744.2.3Polymerization Mechanism754.3CATIONIC POLYMERIZATION764.3.1Initiators for Cationic Polymerization764.3.2Monomers for Cationic Polymerization784.3.3The Mechanism of Cationic Polymerization784.3.4Special Characteristics of Classical Cationic Polymerizations804.4KINETICS OF IONIC POLYMERIZATION804.4.1Anionic Polymerization814.4.2Cationic Polymerization87Exercises4 91Chapter 5 STEP POLYMERIZATION935.1INTRODUCTION935.1.1Types of Condensation Reactions945.1.2Requirements for High Molecular Weight955.2SPECIFIC CONDENSATION POLYMERIZATIONS955.2.1Linear Polyesters955.2.2Branched and Crosslinked Polyesters965.2.3Polycarbonates975.2.4Polyamides(nylons)985.3KINETICS OF STEP POLYMERIZATION995.3.1Equal Reactivity of Functional Groups995.3.2Rate of Polymerization Reactions995.3.3Kinetics of Polyesterification1005.4TIME DEPENDENCE OF THE AVERAGE DEGREE OF POLYMERIZATION1035.5MOLECULAR WEIGHT DISTRIBUTIONS1055.6EFFECT OF NONSTOICHIOMETRIC REACTANT RATIOS1085.7BRANCHED AND CROSSLINKED CONDENSATION POLYMERS1115.8THE METHOD OF STEP POLYMERIZATION1145.8.1Melt Condensation Polymerization1155.8.2Solution Polymerization1165.8.3Interfacial Polycondensation1165.8.4Solid Phase Polycondensation1175.9RANDOM PREPOLYMERS AND STRUCTURE PREPOLYMERS1185.9.1Random Performed Polymers1185.9.2Structure Prepolymers119Exercises5 122Chapter 6 RING-OPENING POLYMERIZATION1266.1INTRODUCTION1266.2CHARACTERISTICS OF RING-OPENING POLYMERIZATION 1266.3POLYMERIZATION ABILITY OF CYCLIC MONOMERS1276.4THERMODYNAMICS OF RING-OPENING POLYMERIZATION OF CYCLOALKANES1276.5THERMODYNAMIC AND KINETIC CHARACTERISTICS OF CYCLOALKANE POLYMERIZATION1286.6IMPORTANT RING-OPENING POLYMERIZATION IN INDUSTRY1306.6.1Cyclic Ether1306.6.2Cationic Ring-opening Polymerization of Carbonyl Compounds and Acetals1336.6.3Ring-opening Polymerization of Cyclic Amides1346.6.4Cyclosiloxane137Exercises6 138Chapter 7 REACTIONS OF SYNTHETIC POLYMERS1397.1REACTIONS INVOLVING THE MAIN CHAIN1397.1.1Addition Reactions1397.1.2Reactions that Generate Skeletal Unsaturation1407.1.3Hydrolytic Chain Cleavage1407.1.4Enzymatic Degradation of Synthetic Polymers1417.1.5Odation Reactions1427.1.6High Temperature Degradation Reactions1437.1.7Electron Beam Depolymerization1477.2REACTIONS INVOLVING THE SIDE GROUPS1477.2.1Principles of Polymer Reactivity1477.2.2Hydrolysis of Side Group Structures1487.2.3Chloromethylation of Polystyrene1507.3GRAFT POLYMER FORMATION1517.4CROSS-LINKING REACTION1527.5SURFACE REACTIONS OF POLYMERS1537.5.1Surface Fluorination1537.5.2Surface Nitrification and Sulfonation1547.5.3Surface Odation154Exercises7 155Chapter 8 METHODS OF POLYMERIZATION1568.1BULK (MASS) POLYMERIZATION1568.2SOLUTION POLYMERIZATION1578.3SUSPENSION POLYMERIZATION1578.4EMULSION POLYMERIZATION1598.4.1Description of Process1608.4.2Quantitative Aspects1688.4.3Other Characteristics of Emulsion Polymerization1768.4.4Soap-Free Emulsion Polymerization1798.4.5Inverse Emulsion Polymerization1808.4.6Miniemulsion Polymerization1818.4.7Microemulsion Polymerization1818.4.8Seed Emulsion Polymerization1818.4.9Core-shell Emulsion Polymerization1828.4.10Dispersion Polymerization1828.4.11Living Radical Polymerization182Exercises8 184REFERENCE185
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