Metal-Promoted Organic Reactions
￥ 33.13 2.6折 ￥ 128 九五品
仅1件
作者Ming Zhang
出版社化学工业出版社
ISBN9787122224453
出版时间2014-12
版次1
装帧精装
开本16开
纸张胶版纸
页数162页
定价128元
上书时间2024-08-11
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基本信息
书名:Metal-Promoted Organic Reactions
定价：128.00元
作者:Ming Zhang
出版社：化学工业出版社
出版日期：2014-12-01
ISBN：9787122224453
字数：
页码：162
版次：1
装帧：精装
开本：16开
商品重量：
编辑推荐
本书作者自20世纪80年代至今一直从事有机化学的研究工作，本图书中特别对碳-氢活化进行了一些解读，同时介绍了一些关于茂金属化合物的合成及其应用的内容，它是金属有机化学的重要组成部分，这些内容都包含了作者本人的独到见解，具参考意义。
内容提要
本书重点介绍金属促进的有机化学反应，全书由八部分组成，内容包括过渡金属催化的通过SP2C-H官能化合成杂环化合物、过渡金属催化的通过SP3C-H官能化合成杂环化合物、铜催化的芳烃C-H官能化、芳烃C-H转化为键、唑类化合物的胺化、杂环化合物不对称官能化、烯烃醛酮和酰胺氢硅化、茂钛族络合物的合成及催化烯烃氢化等，对反应机理进行了详细介绍。反映了相关领域的现状并进行了展望。本书可供从事有机化学、药物化学的科研人员参考，也可作为高等院校高年级本科生及研究生的教学参考书。
目录
1 Heterocycle Synthesis through Direct Coupling of Aromatic and Vinylic C-H Bonds1.1Introduction11.2Construction of carbazoles21.2.1Tandem CH functionalization and CN bond formation21.2.2Pd (OAc)2 catalyzed oxidative biaryl synthesis81.3Construction of benzoxazoles111.4Construction of benzimidazoles141.5Construction of 2substituted benzothiazoles171.6Construction of 3aryl/alkylindazoles191.7Construction of indoles 211.8Construction of indole derivatives oxindoles and indolines261.8.1Construction of oxindoles261.8.2Construction of indolines281.9Construction of benzolactams and phthalimides301.10Construction of dibenzofurans341.11Construction of brigehead unsaturated bicyclic enamines351.12Conclusion37References382 Heterocycle Synthesis through Direct Coupling of Saturated C-H Bonds2.1Introduction402.2Intramolecular cyclization402.2.1CC bond formation402.2.2CN bond formation472.2.3CO bond formation532.3Intermolecular cyclization562.3.1Cyclization with insertion of alkenes562.3.2Cyclization with insertion of CO562.3.3Cyclization with insertion of alkynes572.4Conclusions58References593 Direct Coupling of Aromatic C-H Bonds with a Nitrogen Atom3.1Introduction613.2CN bond formation of arenes having directing groups613.2.1Coppercatalyzed/mediated CN bond formation613.2.2Palladiumcatalyzed CN bond formation683.3Copper(Ⅱ) acetatecatalyzed/mediated CN bond formation ofpolyfluoro(chloro)arenes803.4Metalfree CN bond formation of alkyl substituted arenes843.5Conclusion85References864 Direct Coupling of Azole C-H Bonds with Nitrogen Groups4.1Introduction894.2Coppercatalyzed/mediated amination894.3Acidpromoted amination964.4Metalfree amination1034.5Conclusion107References1075 Copper-Promoted Direct sp2C-H Bond Transformatio5.1Introduction1105.2Aromatic ring CH bond functionalization1115.2.1Cyclization CH bond functionalization1115.2.2Noncyclization CH bond functionalization1165.3Heteroaromatic CH bond functionalization1235.3.1Arylation of heteroaromatic CH bonds1235.3.2Alkenylation of oxazoles with bromoalkenes1305.3.3Amination of heteroaromatic CH bonds1325.4Conclusion134References1346 lron Catalysis for Hydrosilyaltio6.1Introduction1366.2Hydrosilylation of olefins1376.3Hydrosilylation of aldehydes and ketones1396.4Hydrosilylation reduction of amides to amines1446.5Conclusion146References1477 Stereoselective Formation Chiral Heterocyclic Compounds via Cross Dehydrogenative Coupling Reactions of sp3C-H Bonds7.1Introduction1497.2Coppercatalyzed synthesis of tetrahydroisoquinolinederivatives1497.3Organocatalytic synthesis of xanthene and indole derivatives1517.4Coppercatalyzed synthesis of indole derivatives1537.5Conclusion155References1568 Synthesis of Cyclpentadienyl Titanium or Zirconium Complexes and Application in Hydrogenation of Olefins8.1Synthesis of cyclopentadienyl zirconium complexes1578.2Synthesis of cyclopentadienyl titanium complexes1598.3Hydrogenation of olefins using titanocenes160References161
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