聚合物的表征
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作者(美)布伦德尔//埃文斯//周 著作
出版社哈尔滨工业大学出版社
ISBN9787560342849
出版时间2014-01
装帧平装
开本其他
定价118元
货号1200940028
上书时间2024-11-26
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目录
Preface to the Reissue of the Materials Characterization Series
Preface to Series
Preface to the Reissue of Characterization ofPOLYMERs
Preface
Contributors
POLYMER STRUCTURES AND SYNTHESIS METHODS
1.1 Introduction
1.2 Chain Structures in Natural and SyntheticPOLYMERs
The Nature ofPolymeric Materials l, The Composition of
POLYMERicMaterials 3, MolecularWeightandltsDistribution 11,
POLYMERChainConfigurations 12,POLYMERChainConformations 14,
POLYMER SolidPState Struaure, Morphology, and Transitions 15,
POLYMER Surface Struaure
1.3POLYMERSynthesis
ChainReactionPolymerization 21, CoordinationPolymerization 24,
Step ReactionPOLYMERization
1.4 Summary
POLYMER FABRICATION TECHNIQUES
2.1 Introduction
2.2 ProcessingTechniques
FoamProcessing 31, Film-FormingProcesses 31, Composites 32,
Extrusion 34, Molding 35, Coatings 36, OtherMethods
2.3 Applications
Development of Spray-On Insulation for the Thermal Protection System
Of the External Tankin the Space Shuttle Program 37, Development
of Thick, Thin, and Ultrathin Polyimide Films 40, Langmuir-Blodgett
（L-B）Films 47,POLYMERComposites 49, MoldingProcesses 55,
Fiber Drawing and Surface Modification Processes
CHEMICAL COMPOSITION OFPOLYMERS
3.1 Introduction
3.2 ChemicalComposition:Questions toAsk
3.3 Techniques for Determination ofChemical Composition:
What to Use to Ask the Questions
3.4 Illustrative Examples ofCharacterization ofChemical
CompositionofPolymers
Stoichiometry 72, Functionaliry 73, PhaseSeparation 80, Surface
Modification 81, InterfacialChemicalComposition 83, Impurities
3.5 Summary: New Horizons
CHARACTERIZATION OF THE MORPHOLOGY OFPOLYMER SURFACES,INTERFACES, AND THIN FILMS BY MICROSCOPY TECHNIQUES
4.1 0verviewofPolymerlnterfaces andThin Films
4.2 IntroductiontoMicroscopyTechniques
4.3 0pticalMicroscopy
4.4 ScanningElectronMicroscopy
Low-Voltage High-Resolution Scanning Electron Microscopy
Environmental Scanning Electron Microscopy
4.5 Transmission ElectronMicroscopy
4.6 ScanningProbeMicroscopy
4.7 NewMicroscopies
STRUCTURE AND MORPHOLOGY OF INTERFACES AND THIN FILMS BY SCATTERING TECHNIQUES
5.1 Introduction
5.2 IndustriaIApplications
Adhesion 122, BiomedicaIApplications 124, Langmuir-Blodgett Films and OtherThin Films
5.3 IntegratedOpticsMethod
Wave-Guiding 127, NonlinearOpticaIMethod
5.4 Rflectivity
5.5 GrazingIncidenceX-RayScattering
SURFACE THERMODYNAMICS
6.1 Introduction 150
6.2 Theory of Wetting, Spreading, and Adhesion 151
6.3 Experimental Methods 154
Contact Angles 154, Adsorption and Calorimetry 157, Inverse Gas
Chromatography 162, Infrared (FTIR) Spectroscopy 164
SURFACE MODIFICATION OFPOLYMERS
7.1 Introduction 169
7.2 Wet-Chemical Modification ofPOLYMER Surfaces 171
Surface Roughening and Seeding in Placing Operations 171, Surface
Treatment for Bondability 173, Surface Treatment Using Adhesion
Promoters 175, Surface Modification by Photochemical Methods 177
7.3 Dry Modification Techniques 179
Modification by High- and Low-Energy Ion Beams 179, Plasma
Modification ofPOLYMER Surfaces 187, Other Dry Treatment
Techniques 191
7.4 Summary 192
ADHESION
8.1 Introduction 198
8.2 Physical Meaning of Adhesion 200
8.3 Theoretical Analysis of Adhesion 200
8.4 Experimental Measurement of Adhesion 203
8.5 Standardization of Test Procedure 205
8.6 Locus of Failure 205
8.7 Key Adhesion Issues 207
8.8 Illustrative Examples 208
8.9 Summary 209
CHEMISTRY, REACTIVITY, AND FRACTURE OFPOLYMER
INTERFACES
9.1 Introduction 215
9.2 Polyimide Structure and Properties 218
9.3POLYMER-Polymer Interfaces 222
9.4 Metal-Polymer Interfaces 224
9.5POLYMER-Metal Interfaces 230
9.6 Thermal Stress and Interfacial Fracture 234
THEPOLYMER-POLYMER INTERFACE
10.1 Introduction 244
10.2 Techniques for Measuring Diffusion Distances Much
Greater Than Molecular Size 247
10.3 Techniques for Measuring Concentration Profiles on the
Order of Molecular Size 252
10.4 Summary 259
FRICTION AND WEAR (TRIBOLOGY)
11.1 Introduction 262
11.2 Basic Concepts 263
11.3 Tribological Applications 264
11.4 Mechanisms of Friction and Wear 265
Friction 266, Wear 268
11.5 Correlation of Properties with Friction and Wear 269
Energy-to-Rupture and Abrasive Wear 269, Cohesive Energy and
Abrasive Wear 271, Ratio of Applied Stress to Failure Strength and
Wear 271, Molecular Weight and Wear 271, Crystallinity and
Wear 273, Loss Tangent and Friction 273, Closure 274
11.6 Measurement of Friction and Wear 274
ASTM Laboratory Tests 276, Designing Laboratory Tests 284
11.7 Reporting and Interpretation of Measurements 291
11.8 Summary 293
REFERENCES FOR FUTURE STUDY 295
Index 311
内容摘要
《聚合物的表征》内容介绍：characterization of polymers is a practical guide for polymer researchers and technologists who are themselves not specialists in polymer characterization. it will help them determine what surface， interfacial and micro properties are important to their applications and the techniques most suited to the measurement of such properties. unlike other polymer characterization books wherein the primary focus is on techniques rather than material properties，this book emphasizes the properties and their technical implications，and recommends a technique or a range of techniques to measure a specific property complete with the pros and cons of the techniques and methods of data reduction/interpretation wherever pertinent. both widely accepted and novel techniques that may soon become industry norms are covered，and references are given for more in-depth studies.
《聚合物的表征》的作者是布伦德尔、埃文斯、周。
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