Ⅰ Inorganic Chemistry1 Chapter 1 Introduction2 1.1 Observations and Conclusions3 1.2 The Scientific Method3 1.3 Units of Measurement5 1.4 Advice on Studying Chemistry8 Key Words8 Chapter 2 Structures of Atoms9 2.1 Particles in Atoms10 2.2 The Bohr Model12 2.3 The Wave Theory of Electrons13 2.4 Heisenbergs Uncertainty Principle14 2.5 The Schrdinger Equation14 2.6 Quantum Numbers15 2.7 Shapes of Atomic Orbitals17 2.8 Many-Electron Atoms19 2.9 Valence Electrons24 2.10 The Periodic Table and Electronic Configurations of Atoms24 2.11 The Periodicity of the Properties of Elements and Atomic Structure26 Key Words30 Exercises31 Chapter 3 Chemical bonds33 3.1 Ionic Bonds33 3.2 Covalent Bonds35 3.3 Lewis Dot Symbols and Lewis Structure37 3.4 Sigma and Pi Bonds43 3.5 Bond Polarity44 3.6 Bond Energy, Bond Length and Bond Angle45 3.7 Molecular Geometry47 3.8 The VSEPR Model47 3.9 Hybrid Orbitals51 3.10 Molecular Orbitals56 3.11 Intermolecular Force64 Key Words71 Exercises71 Chapter 4 Thermochemistry74 4.1 First Law of Thermodynamics74 4.2 Enthalpy and Enthalpy Change75 4.3 Hesss Law76 4.4 Entropy and the Second Law of Thermodynamics 79 4.5 Spontaneous Processes and Gibbs Free Energy80 4.6 Temperature and Direction of Spontaneous Change81 4.7 Standard Free Energy of Formation and Standard Free Energy of Reaction82 Key Words83 Exercises83 Chapter 5 Chemical Kinetics85 5.1 Reaction Rates85 5.2 Theories of Reaction Rates 87 5.3 Effect of Concentration on Rate of Reaction89 5.4 Rate and Temperature92 5.5 Catalysis94 Key Words95 Exercises96 Chapter 6 Chemical Equilibrium98 6.1 Concept of Equilibrium98 6.2 Equilibrium Constant98 6.3 Le Chteliers Principle103 Key Words106 Exercises106 Chapter 7 Solutions108 7.1 Ways of Expressing Concentration108 7.2 Colligative Properties113 Key Words124 Exercises125 Chapter 8 Solubility Equilibrium127 8.1 Saturated Solutions and Solubility127 8.2 Solubility Equilibria127 8.3 Factors Affecting Solubility130 8.4 Predicting Precipitation Reaction132 8.5 Selective Precipitation134 8.6 Application of Precipitate on Medicine137 Key Words138 Exercises139 Chapter 9 Acid-Base Equilibria141 9.1 Acids and Bases141 9.2 Ion Product of Water143 9.3 Strength of Weak Acids and Bases144 9.4 The pH of Weak Acids and Bases146 9.5 The Common-Ion Effect148 9.6 Buffer Solutions150 Key Words153 Exercises153 Chapter 10 An Introduction to Electrochemistry155 10.1 Oxidation-Reduction Reactions155 10.2 Balancing Oxidation-Reduction Equations158 10.3 Voltaic Cells161 10.4 Standard Cell Electromotive Force164 10.5 Electrochemistry and Thermodynamics171 10.6 Effect of Concentration on Cell EMF172 10.7 Reduction Potential Diagrams of Elements(Latimer Diagrams)174 Key Words177 Exercises177 Chapter 11 Chemistry of Coordination Compounds180 11.1 The History of Coordination Chemistry180 11.2 Formation of Coordination Compound182 11.3 Nomenclature of Coordination Compounds184 11.4 Structure and Isomerism 185 11.5 Coordination Equilibrium in Solution187 11.6 Valence Bond Theory of Coordination Compounds191 11.7 The Crystal Field Theory194 11.8 The Biological Effects of Coordination Compounds199 Key Words200 Exercises201 Chapter 12 Nonmetals and Semimetals203 12.1 General Concepts203 12.2 Hydrogen203 12.3 Boron204 12.4 The Group ⅣA Elements,the Carbon Group Elements205 12.5 The GroupⅤA Elements,the Nitrogen Group Elements208 12.6 The Group ⅥA Elements,the Oxygen Group Elements211 12.7 The Group ⅦA Elements,the Halogens215 12.8 The Group ⅧA Elements,the Noble Gases218 Key Words218 Exercises219 Chapter 13 Metals 220 13.1 The Group IA Elements220 13.2 The Group ⅡA Elements224 13.3 The Group ⅢA Elements229 13.4 A Survey of Transition Metals232 13.5 Chemistry of Some Transition Metals234 Key Words239 Exercises239 Ⅱ Inorganic Chemical Experiments241 Chapter 1 Basic Techniques of Experimental Chemistry242 1.1 Safety242 1.2 Recording Results243 1.3 Weighing243 1.4 Concerning Liquids244 Chapter 2 Typical Chemical Laboratory Apparatus 252 Chapter 3 Experiments254 3.1 Some Elementary Operation254 3.2 Acid-Base Titration256 3.3 Electrolyte Solutions259 3.4 Preparation of Officinal Sodium Chloride and Its Purity Examination 262 3.5 Oxidation-Reduction Reactions267 3.6 Coordination Compounds271 3.7 The Halogens275 3.8 Chromium,Manganese and Iron278 3.9 Copper,Silver,Zinc and Mercury283 3.10 Determination of the Ionization Constant of HAc by pH Meter287 3.11 Preparation of Ammonium Iron(Ⅱ)Sulfate291 3.12 Preparation and Content Determination of Zinc Gluconate294 Appendix296 Reference
鉴于医药学专业学生理论与实验课程并重的特点,全书包含两大部分:Ⅰ Inorganic Chemistry与Ⅱ Inorganic Chemical Experiments。Part Ⅰ includings thirteen chapters:1 Introduction,2 Structures of Atoms,3 Chemical bonds,4 Thermochemistry,5 Chemical Kinetics,6 Chemical Equilibrium,7 Solutions,8 Solubility Equilibrium,9 AcidBase Equilibria,10 An Introduction to Electrochemistry,11 Chemistry of Coordination Compounds,12 Nonmetals and Semimetals,13 Metals。Part Ⅱ includings three chapters:1 Basic Techniques of Experimental Chemistry,2 Typical Chemical Laboratory Apparatus,3 Experiments。
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