目录 Chapter 1 Introduction 1.1 The Category of Chemical Engineering Thermodynamics 1.2 The Role of Thermodynamics in Chemical Engineering 1.3 Fundamental Law of Thermodynamics 1.4 Application of Chemical Engineering Thermodynamics 1.5 The State and System Chapter 2 The Physical Properties of Pure Substances 2.1 Pure Substance 2.2 Phases of Pure Substance 2.3 Phase-change Processes of Pure Substances 2.4 Property Diagrams for Phase-Change Processes 2.4.1 The T-V Diagram 2.4.2 The p-V Diagram 2.4.3 The p-T Diagram 2.4.4 The p-V-T Surface 2.5 Equation of State 2.5.1 The Ideal-Gas Equation of State 2.5.2 Nonideality of Gases 2.6 Other Equations of State 2.6.1 The van der Waals Equation of State 2.6.2 Redlich-Kwong (RK) Equation of State 2.6.3 The Soave-Redlich-Kwong (SRK) Equation of State 2.6.4 Peng-Robinson (PR) Equation of State 2.6.5 Virial Equation of State 2.6.6 Multiparameter Equation of State 2.7 Principle of Corresponding States and Generalized Association 2.7.1 Principle of Corresponding States 2.7.2 Principle of Corresponding States with Two Parameters 2.7.3 Principle of Corresponding States with Three Parameters 2.7.4 Generalized Compressibility Factor Graph Method 2.7.5 Generalized Virial Coefficient Method 2.8 Application of Aspen Plus in Calculation of Thermodynamic Equation of State EXERCISES REFERENCES Chapter 3 Thermodynamic Properties of Pure Fluids 3.1 Mathematical Relationship between Functions 3.1.1 Partial Differentials 3.1.2 Partial Differential Relations 3.1.3 Fundamental Thermodynamic Relation 3.2 The Maxwell Relations 3.3 The Clapeyron Equation 3.4 General Relations for dU, dH, dA, and dG 3.5 Joule-Thomson Coefficient 3.6 The ?H, ?U, and ?S of Real Gas 3.7 Application of Aspen in Thermodynamic Properties CONCLUSION EXERCISES REFERENCES Chapter 4 The Thermodynamics of Multicomponent Mixtures 4.1 Excess Property
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