烟火化学的基本原理与理论
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作者(美)约翰·A.康克林//克里斯托弗·J.莫西拉|译者:代梦艳//张兴高//张开创//李剑斌//赵建峰等
出版社国防工业
ISBN9787118132731
出版时间2024-04
装帧平装
开本其他
定价119元
货号32148110
上书时间2024-11-18
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作者简介
张兴高,工学博士,副研究员,天津大学兼职导师,主要研究方向为烟火技术。2009年博士毕业于国防科技大学材料工程与应用化学系,2013年获院优秀科技干部标兵。作为项目负责人主持完成国家自然科学基金、武器装备科研重点项目共四项,目前作为项目负责人主持“十三五”预研项目1项,参与武器装备科研重点项目3项,获得军内科技进步二等奖2项,三等奖2项,发表论文二十余篇。
目录
第1章 引言.....................................................................................................................................1 含能材料入门................................................................................................................1 黑火药:最初的烟火药................................................................... ..........................3 简短的历史与文化意义...................................................................... .....................5第2章 基本化学原理......................................................... ..........................................................9原子和分子......................................................... .................................... ........................9摩尔概念.........................................................................................................................17电子转移反应.......................................................................................... ....................19 氧化还原理论...................................................... ............... .....................19热价键方法:简单但是有效的技术................. ...................................21 反应式平衡....................... ................... ................ .. .. .. .. ......................24 化学复合物是富燃还是富氧........... .................. .. .. .. ......................25 重量比的计算.............. ...................... ...................... .. .. .. .... ................26 分析混合物的价态... ...................... ............... ....... .. .. .. .....................27 三组分系统... ...................... ............................. ... ...... ... ... ... ... ..........27 热价键的使用... ...................... ......................... ... ... ...... ... ... ..............28 额外的热价键问题..................... .................... ... ... ... ... ......................31电化学............................................................................. ... ... ... ... ... ... ... ....................32热力学............................................................................. ... ... .. ... .................................34 热力学引言.......................................................... ... ... ....................................34 生成焓......................................................... ... ... ... ..........................................36化学反应速率...................... .. ............. . . . ................................................................39富能键..................................... . ............. . . . ................................................................42物质的状态..................................... . ............................................................................43 气态..................................... . ............................................................................44 液态..................................... . ............................................................................45 固态..................................... . ............................................................................46 物质的其他相态.......... . . .............................................................................48酸和碱........................................... . .............................................................................48光辐射........................................... . .............................................................................50 分子辐射................................ . ...........................................................................53 黑体辐射发射....................... ...........................................................................54绿色化学和烟火药:引言......... . ............................................................................54化学原则:最后的注释. ............... . ............................................................................55第3章 含能组分........................................... ............................................................................57引言........................................... . ... ...............................................................................58氧化剂........................................... .. ...............................................................................60硝酸钾........................................... .. ...............................................................................60氯酸钾........................................... .. ...............................................................................64高氯酸钾.........................................................................................................................64绿色烟火药:高氯酸盐系列......................................................................................68高氯酸铵........................................................................... ...............................................71高氯酸铵的新系列.........................................................................................................72二硝基亚胺:高氯酸盐的绿色取代..........................................................................73高碘酸盐:高氯酸盐的绿色取代................................... .........................................745-氨基四唑:高氯酸盐的绿色取代..........................................................................75硝酸锶........................................... .. ...............................................................................75硝酸钡........................................... .. ...............................................................................76氧化铁........................................... .. ...............................................................................76其他氧化剂........................................................................................................................77无氧的氧化剂...................................................................................................................78氧化剂及他们使用摘要................................................................................................78氧化剂选择及对比................................................. .. .. .. .. .........................................79燃料........................................... . ... ................................................. ................................79需求........................................... . ... ................................................. ................................79金属燃料说明...................................................................................................................81铝........................................... . ... .................................................. .. ...............................83镁........................................... . ... .................................................. .. ...............................84镁的重生:烟火药的循环再利用.......................................... .. ..............................85镁合金(镁铝合金).....................................................................................................85铁........................................... . ... ............................................... .. ..................................86其它金属...........................................................................................................................86非金属燃料引言..............................................................................................................87硫磺........................................... . ... ......................................... ........................................87硼.......................................... . ... ......................................... . .. ........................................89硅........................................ . ... .................................................. .. .. ...............................90磷........................................ . ... .............................................................. .... ...................91硫化物........................................ . ... ...............................................................................92有机燃料引言.................................................................................. ..............................92天然有机燃料:虫漆和红胶........................................................................................94木炭............................................................ ... ... ... ... ... ... ... ... ... .................................94淀粉........................................... . ... .................................................. ..............................95其它有机燃料..................................................................................... ...........................96粘合剂......................................... . ... ...............................................................................97粘合剂综述...................................... ...............................................................................97多数粘合剂也是燃料..................................................................................................101延缓剂......................................... . .................................................................................102有色染料的简短说明..................................................................................................103催化剂......................................... ... ...............................................................................104气体量的考虑:回顾....................................................................................................104例子......................................... . ... ...............................................................................105结论和组分选择的最好实践....................................................................................105第4章 烟火学原理..............................................................
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