国外化学名著系列7（影印版）

图书标准信息

• 作者 [英]科尔-汉密尔顿（Cole-Hamilton D.J.） 著
• 出版社 科学出版社
• 出版时间 2008-03
• 版次 1
• ISBN 9787030211897
• 定价 50.00元
• 装帧 精装
• 开本 16开
• 纸张 胶版纸
• 页数 248页
• 字数 315千字
• 正文语种 英语

【内容简介】

　　本书提出了新的办法来解决从均相催化中分离反应产物的难题。新流程涉及低浸出负载型催化剂，可溶性支持措施，如聚合物和树枝状大分子，不常用的溶剂，例如水，含氟有机物，离子液体和超临界流体。不同于其他书籍，除了所涉及的化学，本书着眼于流程的设计，并与现有流程进行了比较，并给出了实例。内容主要包括：新工艺分离的产品解决方案，含有均相催化剂；催化剂对不溶性或可溶性支持-固定床催化剂-连续流或超滤；双相系统：水-有机氟-有机液体，离子液体-有机液体，超临界流体（单相或双相与水，有机或离子液体）；对比当前的流程，涉及大气或低温蒸馏；考察化学与工艺设计；每种方案的利弊等。
　　本书可供催化化学专业研究生，化工、医药工业科研人员参考使用。

【目录】

CHAPTER1HOMOGENEOUSCATALYSIS-ADVANTAGESANDPROBLEMS
1.1Catalysis
1.2CatalystStability
1.2.1THERMALLYINDUCEDDECOMPOSITION
1.2.2CHEMICALLYINDUCEDDECOMPOSITION
1.2.3PHYSICALLOSSFROMTHEPROCESS
1.3LayoutoftheBook
1.4References

CHAPTER2CLASSICALHOMOGENEOUSCATALYSTSEPARATIONTECHNOLOGY
2.1.1CoverageofChapter
2.2GeneralProcessConsiderations
2.3EverythingisaReactor
2.4OverviewofSeparationTechnologies
2.4.1TRADITIONALCOBALTWITHCATALYSTDECOMPOSITION
2.4.2UNIONCARBIDE-DAVYGASRECYCLEPROCESS
2.4.3LIQUIDRECYCLE
2.4.4BIPHASICSYSTEMS;WATER-ORGANIC
2.4.5INDUCEDPHASESEPARATION
2.4.6NON-AQUEOUSPHASESEPARATION
2.4.6.1NAPSUsingaNon-PolarCatalyst
2.4.6.2NAPSUsingaPolarCatalyst
2.4.6.3LigandStructureandSolubilityProperties

2.5Hypotheticalprocesses-HowMighttheProductheSeparatedfromtheCatalyst
2.5.1PROPENEHYDROFORMYLATION
2.5.21-OCTENEHYDROFORMYLATION
2.5.3ALLYLALCOHOL
2.5.4METHOXYVINYLNAPHTHALENE
2.5.5SEPARATIONTECHNOLOGYFORLESSSTABLECATALYSTS
2.5.5.1MitsubishiTPPO/TPPSeparation
2.5.5.2OrganicPolymerforCatalystStabilization

2.6Real-WorldComplications
2.6.1ORGANOPHOSPHORUSLIGANDDEGRADATIONS
2.6.1.1Oxidation
2.6.1.2AlkyldiarylphosphineFormation
2.6.1.3LigandScrambling
2.6.1.4PhosphineReactionswithConjugatedSystems
2.6.1.5PhosphiteOxidation
2.6.1.6SimplePhosphiteHydrolysis
2.6.1.7PoisoningPhosphiteFormation
2.6.1.8AldehydeAcidFormation
2.6.1.9AcidityControl
2.6.2SEPARATINGBYPRODUCTSFROMREACTANTSORPRODUCTS
2.6.2.1AlkeneHydrogenation
2.6.2.2AlkeneIsomerization
2.6.2.3AldehydeDimerizationandTrimerization
2.6.2.4FormationofConjugatedCarbonyls
2.6.3INTRINSICCATALYSTDEACTIVATION

2.7FurtherSeparationChallenges
2.7.1RECOVERYOFMETALVALUESFROMASPENTCATALYST
2.7.1.1CatalystContainmentandCaptureTechnologies
2.8ConcludingRemarks
2.9References

CHAPTER3SUPPORTEDCATALYSTS
ImmobilisationofTailor-madeHomogeneousCatalysts
3.1Introduction
3.2ShortHistoricalOverview
3.3PolystyreneSupportedCatalysts
3.4SilicaSupportedCatalyst
3.5Catalysisinlnterphases
3.6OrderedMesoporousSupport
3.7Non-covalentlySupportedCatalysts
3.8SupportedAqueousPhaseCatalysis
3.9ProcessDesign[71]
3.10ConcludingRemarks
3.11References

CHAPTER4SEPARATIONBYSIZE-EXCLUSIONFILTRATION
HomogeneousCatalystsAppliedinMembraneReactors
4.1Introduction
4.2Reactors
4.2.1DEAD-ENDFILTRATIONREACTORS
4.2.2CROSS-FLOWFILTRATIONREACTORS

4.3Membranes
4.3.1CLASSIFICATIONOFFILTRATIONTYPES
4.3.2MEMBRANEMATERIALS

4.4DendrimerSupportedCatalysts
4.4.1KHARASCHADDITIONREACTION
4.4.2ALLYLICSUBSTITUTIONREACTIONS
4.4.3HYDROVINYLATIONREACTION
4.4.4HYDROGENATIONREACTION
4.4.5MICHAELADDITIONREACTION
4.5DendriticEffects

4.6UnmodifiedorNon-dendriticCatalysts
4.6.1HYDROGENATION
4.6.2PHASETRANSFERCATALYSIS
4.7SolublePolymerSupportedCatalysts
4.8ConcludingRemarks
4.9References

CHAPTER5BIPHASICSYSTEMS：WATER-ORGANIC
5.1Introduction
5.2ImmobilizationwiththeHelpofLiquidSupports
5.2.1GENERAL
5.2.2BIPHASICSYSTEMS
5.2.3AQUEOUSBIPHASICCATALYSIS
5.2.3.1WaterasaSolvent
5.2.3.2Aqueous-phaseCatalysisasaUnitOperation

5.2.4EXAMPLESOFAQUEOUSBIPHASICCATALYSIS
5.2.4.1Itydroformylation(Ruhrchemie/Rh6ne-Poulenc[RCH/RP]process)
5.2.4.2OtherIndustriallyUsedAqueous-biphasicProcesses
5.2.4.3ShortOverviewofOtherReaction
5.2.5OTHERPROPOSALSFORWATER-BIPHASICSYSTEMS
5.2.6INTERLUDE-BIPHASICSYSTEMS：ORGANIC-ORGANIC

5.3RecycleandRecoveryofAqueousCatalysts
5.3.1RECYCLING
5.3.2RECOVERY
5.3.3ECONOMICSOFTHEPROCESS
5.3.4ENVIRONMENTALASPECTS
5.4ConcludingRemarks
5.5References

CHAPTER6FLUOROUSBIPHASICCATALYSIS
6.1Introduction
6.2AlkeneHydrogenation
6.3AlkeneHydrosilation
6.4AlkeneHydroboration
6.5AlkeneHydroformylation
6.6AlkeneEpoxidation
6.7OtherOxidationReactions
6.8AllylicAlkylation
6.9Heck，Stille，Suzuki，SonagashiraandRelatedCouplingReactions
6.10AsymmetricAlkylationofAldehydes
6.11MiscellaneousCatalyticReactions
6.12FluorousCatalysisWithoutFluorousSolvents
6.13ContinuousProcessing
6.14ProcessSynthesisfortheFluorousBiphasicHydroformylationof1-Octene
6.15Conclusions
6.16Acknowledgement
6.17References

CHAPTER7CATALYSTRECYCLINGUSINGIONICLIQUIDS
7.1Introduction
7.1.1INTRODUCTIONT，OIONICLIQUIDS
7.1.2INTRODUCTIONTOTRANSITIONMETALCATALYSISINIONICLIQUIDS
7.1.3MULTIPHASICCATALYSISWITHIONICLIQUIDS-ENGINEERINGASPECTS
7.2Liquid-liquidBiphasic，Rh-catalysedHydroformylationUsingIonicLiquids
7.3RhodiumCatalysedHydroformylationUsingSupportedIonicLiquidPhaseSILP)Catalysis
7.3.1SUPPORTEDIONICLIQUIDSBYCHEMICALBONDS
7.3.2SUPPORTEDIONICLIQUIDSBYIMPREGNATION
7.4CostsAndEconomics
7.5Conclusions
7.6References

CHAPTER8SUPERCRITICALFLUIDS
CompressedGasesasMobilePhaseandCatalystSupport
8.1Introductiontosupercriticalfluids
8.2ApplicationsofscCO2inCatalystImmobilisation
8.2.1CO2ASTHEONLYMASSSEPARATINGAGENT
8.2.2BIPHASICSYSTEMSCONSISTINGOFCO2ANDLIQUIDPHASES
8.2.2.1WaterastheLiquidPhase
8.2.2.2Poly(ethyleneglycol)(PEG)astheLiquidPhase
8.2.2.3lonicLiquidsastheLiquidPhase
8.2.3BIPHASICSYSTEMSCONSISTINGOFCOeANDSOLIDPHASES
8.2.3.1InorganicSupports
8.2.3.2OrganicPolymerSupports
8.3EconomicEvaluationandSummary
8.3.1POTENTIALFORSCALE-UP
8.4Summary
8.5References

CHAPTER9AREASFORFURTHERRESEARCH
9.1Introduction
9.2ConventionalSeparationMethods(SeeChapter2)
9.3CatalystsonInsolubleSupports(Chapter3)
9.4CatalystsonSolubleSupports(Chapter4)
9.5AqueousBiphasicCatalysis(Chapter5)
9.6FluorousBiphasicCatalysis(Chapter6)
9.7ReactionsInvolvingIonicLiquids(Chaoter7)
9.8ReactionsUsingSupercriticalFluids(Chapter8)
9.9Conclusions
9.10References