国外化学名著系列6（影印版）

图书标准信息

• 作者 范立文 著
• 出版社 科学出版社
• 出版时间 2008-03
• 版次 1
• ISBN 9787030211859
• 定价 78.00元
• 装帧 平装
• 开本 16开
• 纸张 胶版纸
• 页数 407页
• 字数 630千字
• 正文语种 简体中文

【内容简介】

《国外化学名著系列6(影印版)》基于作者在教学及工业实践方面广泛的经验，探讨了许多新的和旧的重要反应。每章均以基础知识开始，以最新的内容结束。《国外化学名著系列6(影印版)》侧重于要领但也列举了许多实验室合成有机化学品的关键工业流程和应用流程。全书涵盖精细化学品，大宗化学品，聚合物，高技术聚合物，药品，也包括重要的技巧和反应类型等。同时还介绍了一些反应过程、环境问题和安全问题。

【目录】

Preface
Acknowledgements
1.INTRODUCTION
1.1CATALYSIS
1.2HOMOGENEOUSCATALYSIS
1.3HISTORICALNOTESONHOMOGENEOUSCATALYSIS
1.4CHARACTERISATIONOFTHECATALYST
1.5LIGANDEFFECTS
1.5.1Phosphinesandphosphites：electroniceffects
1.5.2Phosphinesandphosphites：stericeffects
1.5.3LinearFreeEnergyRelationships
1.5.4Phosphinesandphosphites：biteangleeffects

1.6LIGANDSACCORDINGTODONORATOMS
1.6.1Anionicandneutralhydrocarbylgroups
1.6.2Alkoxyandimidogroupsasanionicligands
1.6.3Amines，imines，oxazolinesandrelatedligands
1.6.4Phosphines，phosphites，phosphorusamides，phospholesandrelatedligands
1.6.5Carbenes，carbonmonoxide
1.6.6Commonanions

2.ELEMENTARYSTEPS
2.1CREATIONOFA"VACANT"SITEANDCO-ORDINATIONOFTHESUBSTRATE
2.2INSERTIONVERSUSMIGRATION
2.3β-ELIMINATIONANDDE-INSERTION
2.4OXIDATIVEADDITION
2.5REDUCTIVEELIMINATION
2.6α-ELIMINATIONREACTIONS
2.7CYCLOADDITIONREACTIONSINVOLVINGAMETAL
2.8ACTIVATIONOFASUBSTRATETOWARDNUCLEOPHILICATTACK
2.8.1Alkenes
2.8.2Alkynes
2.8.3Carbonmonoxide
2.8.4Othersubstrates
2.9a-BONDMETATHESIS
2.10DIHYDROGENACTIVATION

2.11ACTIVATIONBYLEWISACIDS
2.11.1Diels-Alderadditions
2.11.2Epoxidation
2.11.3Estercondensation
2.12CARBON-TO-PHOSPHORUSBONDBREAKING
2.13CARBON-TO-SULFURBONDBREAKING
2.14RADICALREACTIONS

3.KINETICS
3.1INTRODUCTION
3.2TWO-STEPREACTIONSCHEME
3.3SIMPLIFICATIONSOFTHERATEEQUATIONANDTHERATEDETERMININGSTEP
3.4DETERMININGTHESELECTIVITY
3.5COLLECTIONOFRATEDATA
3.6IRREGULARITIESINCATALYSIS

4.HYDROGENATION
4.1WILKINSONSCATALYST
4.2ASYMMETRICHYDROGENATION
4.2.1Introduction
4.2.2Cinnamicacidderivatives
4.2.3Chlorideversusweaklycoordinatinganions;alkylphosphinesversusarylphosphines
4.2.4Incubationtimes

4.3OVERVIEWOFCHIRALBIDENTATELIGANDS
4.3.1DUPHOS
4.3.2BINAPcatalysis
4.3.3Chiralferrocenebasedligands
4.4MONODENTATELIGANDS
4.5NON-LINEAREFFECTS
4.6HYDROGENTRANSFER

5.ISOMERISATION
5.1HYDROGENSHIFTS
5.2ASYMMETRICISOMERISATION
5.3OXYGENSHIFTS

6.CARBONYLATIONOFMETHANOLANDMETHYLACETATE
6.1ACETICACID
6.2PROCESSSCHEMEMONSANTOPROCESS
6.3ACETICANHYDRIDE
6.4OTHERSYSTEMS
6.4.1Higheralcohols
6.4.2Phosphine-modifiedrhodiumcatalysts
6.4.3Othermetals

7.COBALTCATALYSEDHYDROFORMYLATION
7.1INTRODUCTION
7.2THERMODYNAMICS
7.3COBALTCATALYSEDPROCESSES
7.4COBALTCATALYSEDPROCESSESFORHIGHERALKENES
7.5KUHLMANNCOBALTHYDROFORMYLATIONPROCESS
7.6PHOSPHINEMODIFIEDCOBALTCATALYSTS：THESHELLPROCESS
7.7COBALTCARBONYLPHOSPHINECOMPLEXES
7.7.1Carbonylspecies
7.7.2Phosphinederivatives

8.RHODIUMCATALYSEDHYDROFORMYLATION
8.1INTRODUCTION
8.2TRIPHENYLPHOSPHINEASTHELIGAND
8.2.1Themechanism
8.2.2Ligandeffectsandkinetics
8.2.3Regioselectivity
8.2.4Processdescription，rhodium-tpp
8.2.5Two-phaseprocess，tppts：Ruhrchemie/Rhone-Poulenc
8.2.6One-phasecatalysis，two-phaseseparation
8.3DIPHOSPHINESASLIGANDS
8.3.1Xantphosligands：tuneablebiteangles

8.4PHOSPHITESASLIGANDS
8.4.1Electroniceffects
8.4.2Phosphites：stericeffects
8.5DIPHOSPHITES

8.6ASYMMETRICHYDROFORMYLATION
8.6.1Rhodiumcatalysts：diphosphites
8.6.2Rhodiumcatalysts：phosphine-phosphiteligands

9.ALKENEOLIGOMERISATION
9.1INTRODUCTION
9.2SHELL-HIGHER-OLEFINS-PROCESS
9.2.1Oligomerisation
9.2.2Separation
9.2.3Purification，isomerisation，andmetathesis
9.2.4Newcatalysts
9.3ETHENETRIMERISATION
9.4OTHERALKENEOLIGOMERISATIONREACTIONS

10.PROPENEPOLYMERISATION
10.1INTRODUCTIONTOPOLYMERCHEMISTRY
10.1.1IntroductiontoZieglerNattapolymerisation
10.1.2Historyofhomogeneouscatalysts

10.2MECHANISTICINVESTIGATIONS
10.2.1Chain-endcontrol：syndiotacticpolymers
10.2.2Chain-endcontrol：isotacticpolymers

10.3ANALYSISBY13CNMRSPECTROSCOPY
10.3.1Introduction
10.3.2Chain-endcontrol
10.3.3Sitecontrolmechanism

10.4THEDEVELOPMENTOFMETALLOCENECATALYSTS
10.4.1Sitecontrol：isotacticpolymers
10.4.2Sitecontrol：syndiotacticpolymers
10.4.3Doublestereoselection：chain-endandsitecontrol
10.5AGOSTICINTERACTIONS
10.6THEEFFECTOFDIHYDROGEN
10.7FURTHERWORKUSINGPROPENEANDOTHERALKENES
10.8NON-METALLOCENEETMCATALYSTS
10.9LATETRANSITIONMETALCATALYSTS

11.HYDROCYANATIONOFALKENES
11.1THEADIPONITRILEPROCESS
11.2LIGANDEFFECTS

12.PALLADIUMCATALYSEDCARBONYLATIONSOFALKENES
12.1INTRODUCTION
12.2POLYKETONE
12.2.1Backgroundandhistory
12.2.2Elementarysteps：initiation
12.2.3Elementarysteps：migrationreactions
12.2.4Elementarysteps：chaintermination，chaintransfer
12.2.5Elementarysteps：esterformationaschaintermination

12.3LIGANDEFFECTSONCHAINLENGTH
12.3.1Polymers
12.3.2Ligandeffectsonchainlength：Propanoate
12.3.3Ligandeffectsonchainlength：Oligomers
12.4ETHENE/PROPENE/COTERPOLYMERS
12.5STEREOSELECTIVESTYRENE/COCOPOLYMERS

13.PALLADIUMCATALYSEDCROSS-COUPLINGREACTIONS
13.1INTRODUCTION
13.2ALLYLICALKYLATION
13.3HECKREACTION
13.4CROSS-COUPLINGREACTION
13.5HETEROATOM-CARBONBONDFORMATION
13.6SUZUKIREACTION

14.EPOXIDATION
14.1ETHENEANDPROPENEOXIDE
14.2ASYMMETRICEPOXIDATION
14.2.1Introduction
14.2.2Katsuki-Sharplessasymmetricepoxidation
14.2.3TheJacobsenasymmetricepoxidation
14.3ASYMMETRICHYDROXYLATIONOFALKENESWITHOSMIUMTETROXIDE
14.3.1Stoichiometricreactions
14.3.2Catalyticreactions
14.4JACOBSENASYMMETRICRING-OPENINGOFEPOXIDES
14.5EPOXIDATIONSWITHDIOXYGEN

15.OXIDATIONWITHDIOXYGEN
15.1INTRODUCTION
15.2THEWACKIERREACTION
15.3WACKIERTYPEREACTIONS
15.4TEREPHTHALICACID
15.5PPO

16.ALKENEMETATHESIS
16.1INTRODUCTION
16.2THEMECHANISM
16.3REACTIONOVERVIEW
16.4WELL-CHARACTERISEDTUNGSTENANDMOLYBDENUMCATALYSTS
16.5RUTHENIUMCATALYSTS
16.6STEREOCHEMISTRY
16.7CATALYSTDECOMPOSITION
16.8ALKYNES
16.9INDUSTRIALAPPLICATIONS

17.ENANTIOSELECTIVECYCLOPROPANATION
17.1INTRODUCTION
17.2COPPERCATALYSTS
17.3RHODIUMCATALYSTS
17.3.1Introduction
17.3.2Examplesofrhodiumcatalysts

18.HYDROSILYLATION
18.1INTRODUCTION
18.2PLATINUMCATALYSTS
18.3ASYMMETRICPALLADIUMCATALYSTS
18.4RHODIUMCATALYSTSFORASYMMETRICKETONEREDUCTION

19.C-HFUNCTIONALISATION
19.1INTRODUCTION
19.2ELECTRON-RICHMETALS
19.3HYDROGENTRANSFERREACTIONSOFALKANES
19.4BORYLATIONOFALKANES
19.5THEMURAIREACTION
19.6CATALYTICa-BONDMETATHESIS
19.7ELECTROPHILICCATALYSTS
SUBJECTINDEX