作者简介 Paul H.HOlloway and P.N.Vaidyanathan,Characterization of MetaIs and Alloys provides an introduction to su rface andinterface analysis techniques for spets and educated professional metalIu rgists or scientists.ThiS book iIIustrates with case histories how characterization techniques can be used to determjBe important properties of metals andprovides a systematic approach to the task of correlatjng structure and composition with properties(mechanical,chemical,and physical properties,anddiffusion and phase transformations in metals).This IS a useful reference bookfor practicaI engineers and SCientists who want to learn what can be accomPIished with modern analyticaI techniques,or who want trOubIeshooting adviceon problems involving the structure/property relationships in metals and alIoys.
目录 Preface to the Reissue of the Materials Characterization Series
Preface to Series
Preface to the Reissue of Characterization of Metals andAlloys
Preface
Acronyms Glossary
Contributors
INTRODUCTION
1.1 Purpose and Organization of the Book
MECHANICAL PROPERTIES AND INTERFACIAL ANALYSIS
2.1 Introduction
2.2 Grain Boundary Segregation
2.3 Temper Embrittlement
2.4 Corrosion and Stress Corrosion Cracking
2.5 Hydrogen Embrittlement
2.6 Creep Embrittlement
2.7 Future Directions
CHEMICAL PROPERTIES
3.1 Introduction
3.2 Tools of the Trade--Unique Information Available
3.3 Gaseous Corrosion
3.4 Aqueous Corrosion
3.5 Surface Electronic Structure and Chemistry
3.6 Surface Modification
3.7 Summary
SURFACE AND THIN FILM ANALYSIS OF DIFFUSION IN METALS
4.1 Introduction
4.2 The Mathematics of Diffusion
4.3 Effects of Non-Uniform Cross Sections
4.4 Effects of Finite Thickness
4.5 Analysis Techniques for Diffusion
4.6 Case Studies of Diffusion
4.7 Summary
MINERAL PROCESSING AND METAL RECLAMATION
5.1 Introduction
5.2 Techniques for Mineral Surface Characterization
5.3 Surface Bonding in Mineral-Fluid Systems
5.4 Complementary Composition Analyses of Rough and Polished Surfaces
5.5 Summary
MELTING AND CASTING
6.1 Introduction
6.2 Aluminum-Lithium Alloys
6.3 Aluminum-Magnesium Alloys
6.4 Rapidly Solidified Aluminum Alloy Powders
6.5 Cast Aluminum Alloy Metal Matrix Composites
6.6 Liquid Aluminum Alloys
6.7 Summary
MACHINING AND WORKING OF METALS
7.1 Introduction
7.2 Physical and Chemical Characterization
7.3 Lubrication
7.4 Surface Finish
7.5 Metalworking Example
7.6 Summary
CHARACTERIZATION OF THE CLEANING OF SURFACES OF METALS AND METAL ALLOYS
8.1 Introduction
8.2 Characterization of Cleaning Procedures
8.3 Specimen Handling and Interpretation of Data
8.4 Summary
COATINGS AND THIN FILMS
9.1 Introduction
9.2 Techniques for Creating Coatings and Thin Films
9.3 Techniques to Characterize Coatings and Thin Films
9.4 Studies of Coatings on Metals
9.5 Studies of Thin Films on Metals
9.6 Summary
FAILURE ANALYSIS
10.1 Introduction
10.2 Collaboration with the Applications Engineering Team
10.3 Failure Analysis Case Histories
10.4 Summary
APPENDIX: TECHNIQUE SUMMARIES
1 Auger Electron Spectroscopy (AES)
2 Cathodoluminescence (CL)
3 Dynamic Secondary Ion Mass Spectrometry (Dynamic SIMS)
4 Elastic Recoil Spectrometry (ERS)
5 Electron Energy-Loss Spectroscopy in the Transmission Electron Microscope (EELS)
6 Electron Probe X-Ray Microanalysis (EPMA)
7 Energy-Dispersive X-Ray Spectroscopy (EDS)
8 Extended X-Ray Absorption Fine Structure (EXAFS)
9 Field Ion Microscopy (FIM)
10 Fourier Transform Infrared Spectroscopy (FTIR)
11 Glow-Discharge Mass Spectrometry (GDMS)
12 High-Resolution Electron Energy Loss Spectroscopy (HREELS)
13 Inductively Coupled Plasma Mass Spectrometry (ICPMS)
48 X-Ray Photoelectron and Auger Electron Diffraction (XPD and AED)
49 X-Ray Photoelectron Spectroscopy (XPS)
Index
内容摘要 Techniques such as second harmonic generation, synchrotron based X-rayadsorption spectroscopies, and other optical methods will be used for real-time analysis of processes.
It should also be noted that many users of current methods do not use the techniques to fullest advantage. Considerable additional information can be obtainedby a more complete understanding of technique and existing instrumentation. It ishoped that this chapter will provide some suggestions.
Major advances have been made during the past ten years both in the type ofequipment available and in the understanding of best analysis methods. Areas whichhave seen significant development include decreases in beam size (decrease in analysisarea or analysis volume),~ quantification (understanding of instrument characteris-tics and methods to quantify data),34 development of in situ methods (STM, SHG,FTIR),15-17, 35 improved da
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