相图边界理论及其应用（英文版）

图书标准信息

• 作者 Mu、Lizhu、Xiaobao Fan 著
• 出版社 科学出版社
• 出版时间 2009-01
• 版次 1
• ISBN 9787030244581
• 定价 120.00元
• 装帧 精装
• 开本 16开
• 纸张 胶版纸
• 页数 238页
• 正文语种 英语

【内容简介】

TheBoundaryTheoryofPhaseDiagramsandItsApplicationRulesforPhaseDiagramConstructionwithPhaseRegionsandTheirBoundariespresentsanoveltheoryofphasediagrams.ThoroughlyrevisedonthebasisoftheChineseeditionandrigorouslyreviewed，thisbookinspectsthegeneralfeatureandstructureofphasediagrams，andrevealsthatthereexistactuallytwocategoriesofboundaries.Thisinnovativeboundarytheoryhassolvedmanydifficultiesinunderstandingphasediagrams，andalsofindsitsapplicationinconstructingmulti-componentphasediagramsorincalculatinghigh-pressurephasediagrams.Researchersandengineersaswellasgraduatestudentsintheareasofchemistry，metallurgyandmaterialssciencewillbenefitfromthisbook.Prof.MuyuZhaowastherecipientofthe1998PrizeforProgressinScienceandTechnology（forhisworkontheboundarytheoryofphasediagrams）awardedbytheNationalCommissionofEducation，China，andmanyotherprizes.

【作者简介】

MuyuZhao，CollegeofChemistryJilinUniversityChangchun，130012，ChinaEmail：muyuzhao1929@yahoo.com.cn.
XiaobaoFan，TeknaPlasmaSystems，Inc.Sherbrooke，CanadaEmail：xiaobao.fan@tekna.com.
LizhuSong，CollegeofChemistryJilinUniversityChangchun，130012，ChinaEmail：slz@jlu.edu.cn.

【目录】

Preface
Comment
Introduction

PartOneThePhaseRule，ItsDeductionandApplication

Chapter1ThePhaseRule，ItsDeductionandApplication
1.1WhydoWeDiscussthePhaseRuleatFirst
1.2DifferentMethodsforDeducingthePhaseRule：TheMethodofGibbsHimself，Gibbs-RoozeboomsMethodandtheMethodofGibbsFreeEnergyMinimization
1.3DeterminationoftheNumberofIndependentComponentsbyBrinkley＇sMethod
1.4SomeRemarksontheApplicationofthePhaseRule
References-1
SummaryofPartOne

PartTwoTheBoundaryTheoryofIsobaricPhaseDiagramsandItsApplication

Chapter2TheBoundaryTheoryofIsobaricPhaseDiagrams——RulesforPhaseDiagramConstruction
2.1Introduction
2.2SeveralBasicConceptsforUnderlyingthePhaseDiagram
2.3TheTheoremoftheCorrespondingRelationshipbetweentheTotalNumberofAlltheDifferentPhasesinNPRsφandtheDimensionsofthePhaseBoundaryR1inPhaseDiagrams，andItsTheoreticalDeduction
2.4TheTheoremoftheCorrespondingRelationship（TCR）isanIndependentTheorem，NotaVariantofthePhaseRule
2.5CorollariesofTCRforIsobaricPhaseDiagrams
2.6TheRelationshipbetweentheDimensionsofthePhaseBoundaryR1andtheDimensionsoftheBoundaryR1forIsobaricMulticomponentPhaseDiagrams
2.7TheSummaryoftheBoundaryTheoryofIsobaricPhaseDiagrams
References-2

Chapter3ApplicationoftheBoundaryTheorytoUnary，BinaryandTernaryPhaseDiagramsComparisonoftheBoundaryTheoryApplicationandPalatnik-LandausContactRuleofPhaseRegions
3.1DeterminationofPhaseAssemblagesofNPRsandtheCharacteristicsofTheirBoundariesbytheBoundaryTheory
3.2ApplicationoftheBoundaryTheorytoUnaryPhaseDiagrams
3.3ApplicationoftheBoundaryTheorytoBinaryPhaseDiagrams
3.4ApplicationoftheBoundaryTheorytoTernaryPhaseDiagrams
3.5ExplanationofRhinesTenEmpiricalRulesforConstructing
ComplicatedTernaryPhaseDiagramswiththeBounaryTheory
3.6ComparisonoftheBoundaryTheoryandtheP-LsContactRuleof
PhaseRegions
References-3

Chapter4
TheApplicationoftheBoundaryTheoryofPhaseDiag-ramstotheQuaternaryandHigherNumberComponentPhaseDiagrams
4.1Introduction
4.2TheRelationshipamongNPRsandtheirBoundariesinaTypical，Iso-baric，QuaternaryPhaseDiagram
4.3DuringTemperatureDecreasing，SomeCasesofVariationsoftheNPRs
andtheirBoundaries，MaybeEncounteredforSeveralTypesof
QuaternaryIsobaricPhaseDiagrams
4.4TheIsobaricQuinaryPhaseDiagrams
4.5Conclusion
References-4

Chapter5TheBoundaryTheoryinConstructionofMulticompo-nentIsothermalSections
5.1TheRelationshipamongNeighboringPhaseRegions（NPRs）andTh-eirBoundariesinIsobaricIsothermalMulticomponentSections
5.2TheNon-ContactPhaseRegionsandtheBoundariesbetweenThemContents
5.3ConstructionofanIsothermalQuinarySection，withLimitedInformation
5.4TheMethodofConstructinganIsothermalEight-Componentsection
55SummaryofPartTwoPartThreeTheBoundaryTheorymethod
References-5

Chapter6TheBoundaryTheoryofMulticomponentIsobaricIsoplethSections
6.1Introduction
6.2TheCharacteristicsofBoundariesinIsoplethSectionsfortheCaseofⅣ≥2andR1≥1
6.3TheCharacteristicsofBoundariesintheIsoplethSectionfortheCaseofN≥2，R1=0，thereisnoInvariantPhaseTransitionbetweenthetwoNPRs
6.4TheCase0fN≥2，R1=0，thereisanInvariantPhaseTransitionbetweenthetwoNPRs．InthisCase，theremaybefl，BoundaryLineoraBoundaryPointbetweentwoNPRs
6.5Example
6.6TheTheOrYofTwo～DimensionalSectionsofIsobaricMulticomponentPhaseDiagrams．
References-6

Chapter7TheApplicationoftheBoundaryTheorytoIsobaricPhaseDiagrams
7.1BriefReviewoftheApplicationfortheBoundaryTheory
7.2TheAnalysisoftheFe-Cr-CIsoplethSection。
7.3TheApplicationoftheBoundaryTheorytoPhaseDiagramCalculation
7.4TheApplicationoftheBoundaryTheorytoPhaseDiagramAssessment．
7.5TheApplicationoftheBoundaryTheorytoPhaseDiagramDeterlllinatiOn
7.6TheApplicationoftheBoundaryTheorytoPhaseDiagramEducation．
References-7
Summayofparttwo

PartThreeTheBoundaryTheoryandCalculationofHighPressurePhaseDiagrams

Chapter.8TheBoundaryTheoryforp-T-xiMultieomponentPhaseDiagrams
8.1Introduction
8.2TheTheoremofCorrespondingRelationshipforp-T-xiMulticomponentPhaseDiagramsandItsCorollaries
8.3TheRelationshipbetweenR1andR1inp-T-xiMulticomponentPhaseDiagrams
8.4TheRelationshipamongNPRsandTheirBoundariesforthep-T-xBinaryPhaseDiagrams
8.5RelationshipamongNPRsandtheirBoundariesforthep-T-xiTernaryPhaseDiagram
8.6TheApplicationofBoundaryTheoryforQuaternaryp-T-xiPhaseDiagrams
8.7TheReliabilityoftheBoundaryTheoryofMulticomponentp-T-xiPhaseDiagrams
References-8

Chapter9TheCalculationofUnaryHigh-PressurePhaseDiagra-msandtheBoundaryTheoryofp-TPhaseDiagramsofMultieomponentSystems
9.1Introduction
9.2CalculationofUnaryp-TDiagrams
9.3TheBoundaryTheoryofp-TPhaseDiagramsofMulticomponentSystemswithoutCompositionVariable
References-9

Chapter10CalculationofBinaryHigh-PressurePhaseDiagrams
10.1PrinciplesfortheCalculationofBinaryPhaseDiagramsatElevatedPressures
10.2CalculationoftheStandardMolarGibbsFreeEnergyforthePureComponents
10.3CalculationofActivityCoefficientsγi（T，po，xi）Ofthe/-titComponentintheEquilibriumPhases
10.4PartialMolarVolumes
10.5SomeRemarksontheValuesofaandβ
10.6Example-CalculationoftheCd-PbPhaseDiagramatHighPressure
References-10

Chapter11TheCalculationofHigh-PressureTernaryPhaseDia-grams
11.1TheCharacteristicsoftheBoundariesoftheHigh-PressureTernaryPhaseDiagrams，andtheBasicEquationsforTheirCalculation
11.2TheTreatmentofThermodynamicParametersforTernarySystemsatHighPressure
11.3VerificationoftheEstimationMethodfortheExcessMolarVolumebyExperiment
11.4TheCalculationofHigh-PressurePhaseDiagramsofCd-Pb-SnandCd-Sn-ZnSystems
11.5VerificationofCalculatedHigh-PressureTernaryPhaseDiagramsthroughExperimentalDetermination
11.6TheComparisonbetweentheMethodsofExperimentalDetermina-tionandThermodynamicCalculationofHighPressurePhaseDiagrams
References-11
SummaryofPartThree
ReferencesofThisBook
ImportantSymbols
Index
Annex