目录 Preface PART I QUANTUM STATISTICAL MECHANICS CHAPTER 1 THE LIOUVILLE EQUATION IN CLASSICAL MECHANICS 1.Introduction: Statistical approach in classical and quantum mechanics 2.The classical statistical approach a) A transformation operator G b) Probability density D c) The Liouville theorem d) Time dependent probability density Dt, to 3.Quantum analogy 4.Symmetry properties 5.Isolated dynamical systems 6.A system of identical monoatomic molecules 7.Property of reversibility CHAPTER 2 THE LIOUVILLE EQUATION IN QUANTUM MECHANICS 1.The X-representation 2.Quantum statistical approach a) Statistical operators b) The Liouville equation c) Operator Ut, to d) Properties of the statistical operators 3.Symmetry properties 4.Discrete X-representation 5.Discrete momentum representation 6.Compatibility with the Schroedinger equation 7.Limit transition and cyclic boundary condition 8.An isolated dynamical system 9.Conservation and non-conservation of particle number a) N-particle wave functions b) X-representation for variable particle numbers c) The Hilbert space of wave functions and its subspaces d) A projection operator e) A combined index CHAPTER 3 CANONICAL DISTRIBUTION AND THERMODYNAMIC FUNCTIONS 1.Integrals of motion 2.The Gibbs canonical distribution 3.Thermodynamic functions 4.Quasi-static processes a) The concept of quasi-static process b) Construction of quasi-static processes c) Interpretation of terms d) Heat capacity e) Homogeneous systems f) Relation between H and E 5.Passing to limits a) Basic assumptions b) Boundary surface c) Limits d) Validity of speculations on passing to limits 6.The grand canonical ensemble a) Statistical operators b) Definitions of μ, Γ and G c) Uniqueness of μj PART II SOME ASPECTS OF THE METHOD OF SECONDARY QUANTIZATION PART III QUADRATIC HAMILTONIANS AND THEIR APPLICATION PART IV SUPERFLUIDITY AND QUASI-AVERAGES IN PROBLEMS OF STATISTICAL MECHANICS Photos Index
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