描述有机化学反应机理（第2版）

图书标准信息

• 作者 A·Miller 著
• 出版社 世界图书出版公司
• 出版时间 2004-04
• 版次 2
• ISBN 9787506265959
• 定价 98.00元
• 装帧 平装
• 开本 16开
• 纸张 胶版纸
• 页数 471页

【内容简介】

BookDescription：Inrevisingthistextforthesecondedition,amajorgoalwastomakethebookmoreuser-friendlyforbothgraduateandundergraduatestudents.Introductorymaterialhasbeenfleshedout.Headingshavebeenaddedtomakeiteasiertolocatetopics.Thestructureshavebeenredrawnthroughout,withaddedemphasisonthestereochemicalaspectsofreactionmechanisms.Coverageofsometopicssuchassolventeffectsandneighboringgroupeffectshasbeenexpanded,andChapter6hasbeencompletelyreorganizedandextensivelyrewritten.

【目录】

PrefacetotheSecondEdition
PrefacetoFirstEdition
1Introduction—MolecularStructureandReactivity
1.HowtoWriteLewisStructuresandCalculateFormalCharges
2.RepresentationsofOrganicCompounds
3.GeometryandHybridization
4.ElectronegativitiesandDipoles
5.ResonanceStructures
6.AromaticityandAntiaromaticity
7.TautomersandEquilibrium
8.AcidityandBasicity
9.NucleophilesandElectrophiles
2GeneralPrinciplesforWritingReactionMechanisms
1.BalancingEquations
2.UsingArrowstoShowMovingElectrons
3.MechanismsinAcidicandBasicMedia
4.Electron-RichSpecies：BasesorNucleophiles?
5.TrimolecularSteps
6.StabilityofIntermediates
7.DrivingForcesforReactions
8.StructuralRelationshipsbetweenStartingMaterialsandProducts
9.SolventEffects
10.ALastWord
3ReactionsofNucleophilesandBases
1.NucleophilicSubstitution
2.EliminationsatSaturatedCarbon
……
4ReactionsInvolvingAcidsandOtherElectrophiles
5RadicalsandRadicalAnions
6PericyclicReactions
7AdditionalProblems
AppendixALewisStructuresofCommonFunctionalGroups
AppendixBSymbolsandAbbreviationsUsedinChemicalNotation
AppendixCRelativeAciditiesofCommonOrganicandInorganicSubstances
Index